I guess the real question is if the gap is large enough for two o-rings. It may appear to be so when the original ring is uncompressed, but how much does it expand sideways under compression. Since pressure is applied from the side, so to speak, one o-ring will start to compress before the other. If there is not enough room, the second ring might be forced to remain taller in the groove than is designed, where it could either tear itself or possibly keep the cap from seating all the way due to resistance. Unless one is an o-ring designer, I guess the only real way to test would be to add the second ring, and then open and close the fitting several times, then check for any damage, especially to the inner ring. Truly a trial and error process.